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A Mn(II)/bipyridine-catalyzed bromination reaction of unactivated aliphatic C(sp3)−H bonds has been developed using N-bromosuccinimide (NBS) as the brominating reagent. The reaction proceeded in moderate-to-good yield, even on a gram scale.… Click to show full abstract
A Mn(II)/bipyridine-catalyzed bromination reaction of unactivated aliphatic C(sp3)−H bonds has been developed using N-bromosuccinimide (NBS) as the brominating reagent. The reaction proceeded in moderate-to-good yield, even on a gram scale. The introduced bromine atom can be converted into fluorine and allyl groups.
Keywords:
catalyzed non;
non directed;
bromination;
bipyridine catalyzed;
bipyridine;
manganese bipyridine
Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2021
Link to full text (if available)
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Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2021
Link to full text (if available)
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recommendations!