A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction… Click to show full abstract
A series of 2-(perfluoroalkylthio)benzothiazolium (BT-SRF) salts have been synthesized that serve as convenient sources of hitherto underexplored perfluoroalkylthiolate anions. An investigation of their reactivity in a deoxygenative nucleophilic substitution reaction led to the development of an unprecedented process that provides pentafluoroethyl and heptafluoropropyl thioethers directly from readily available alcohols.
Keywords:
benzothiazolium salts;
perfluoroalkylthiolation alcohols;
reagents deoxygenative;
deoxygenative perfluoroalkylthiolation;
salts reagents;
benzothiazolium
Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2021
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Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2021
Link to full text (if available)
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recommendations!