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An α-cyclodextrin protected with 2,4-dichlorobenzyl groups on the primary alcohols and ordinary benzyl groups on the secondary alcohols was prepared and subjected to DIBAL (diisobutylaluminum hydride)-promoted selective debenzylation. Debenzylation proceeded… Click to show full abstract
An α-cyclodextrin protected with 2,4-dichlorobenzyl groups on the primary alcohols and ordinary benzyl groups on the secondary alcohols was prepared and subjected to DIBAL (diisobutylaluminum hydride)-promoted selective debenzylation. Debenzylation proceeded by first removing two dichlorobenzyl groups from the 6A,D positions and then removing one or two benzyl groups from the 3A,D positions.
Keywords:
benzyl;
selective debenzylation;
benzyl groups;
cyclodextrin protected;
promoted selective
Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2022
Link to full text (if available)
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Journal Title: Beilstein Journal of Organic Chemistry
Year Published: 2022
Link to full text (if available)
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recommendations!