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Mn 2+ -doped CsPbX 3 (X=Cl, Br and I) perovskite nanocrystals and their applications

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Colloidal Mn2+ doped CsPbX3(X=Cl, Br, I) nanocrystals(NCs) are being explored extensively as alternative emitting materials, wherein highly efficient optical and optoelectronic processes can be achieved. Mn2+ doping in perovskite NCs… Click to show full abstract

Colloidal Mn2+ doped CsPbX3(X=Cl, Br, I) nanocrystals(NCs) are being explored extensively as alternative emitting materials, wherein highly efficient optical and optoelectronic processes can be achieved. Mn2+ doping in perovskite NCs also reveals several new fundamental aspects of doping and new dopant-induced optical properties through different methods of synthesis. Mn2+ doping exists in wide-band-gap perovskite hosts where the excitation energy is transferred to an Mn d-state, resulting in short-range tunable yellow-orange d-d emissions. Enormous efforts have been expended on understanding the doping process and designing highly efficient doped NCs. The unique electronic and fluorescent properties endow these Mn2+ doped perovskite NCs with various optoelectronic applications in light-emitting diodes(LEDs) and solar cells. Combining all these facts, this review focuses on the recent progress in synthesis methods, emission mechanism, and potential applications of Mn2+ doped CsPbX3 perovskite NCs and provides an outline for plausible future studies.

Keywords: perovskite ncs; cspbx perovskite; nanocrystals applications; mn2 doped; doped cspbx; perovskite nanocrystals

Journal Title: Chinese Optics
Year Published: 2019

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