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The reaction of oxidation with molecular oxygen in dimethyl sulfoxide is of order one in the metallocenes; the specific reaction constant decreases from nickel, chromium to cobalt. A reaction mechanism… Click to show full abstract
The reaction of oxidation with molecular oxygen in dimethyl sulfoxide is of order one in the metallocenes; the specific reaction constant decreases from nickel, chromium to cobalt. A reaction mechanism is proposed. The values of the polarographic constants and the bond lengths vary linearly with respect to the increase of the specific reaction constant but with opposite slopes.
Keywords:
bond lengths;
reaction;
chromium cobalt;
molecular oxygen
Journal Title: Journal of the Chilean Chemical Society
Year Published: 2019
Link to full text (if available)
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Journal Title: Journal of the Chilean Chemical Society
Year Published: 2019
Link to full text (if available)
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recommendations!