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Effect of macrocycle stereoisomerism on extraction of Li+ cations from chloride media by solutions of dicyclohexano-14-crown-4 in 1,1,7-trihydrododecafluoroheptanol

The new extractant based on dicyclohexano-14-crown-4 solution in 1,1,7-trihydrododecafluoroheptanol is proposed for the removal of lithium cations from the chloride media, such as reservoir waters. The stereoisomerism of the macrocyclic… Click to show full abstract

The new extractant based on dicyclohexano-14-crown-4 solution in 1,1,7-trihydrododecafluoroheptanol is proposed for the removal of lithium cations from the chloride media, such as reservoir waters. The stereoisomerism of the macrocyclic ligand is revealed to be a key factor determining the efficiency and selectivity of this system.

Keywords: effect macrocycle; macrocycle stereoisomerism; stereoisomerism extraction; cations chloride; chloride media; dicyclohexano crown

Journal Title: Mendeleev Communications
Year Published: 2025

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