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First-Order Metal–Semiconductor Transition Triggered by Rattling Transition in Tetrahedrite Cu12Sb4S13: Cu-Nuclear Magnetic Resonance Studies

Tetrahedrite Cu12Sb4S13 shows a metal–semiconductor transition (MST) at TMST = 85 K. We have studied the mechanism of the MST by measurements of Cu-NMR. Above TMST, the Cu-NMR spectrum consists… Click to show full abstract

Tetrahedrite Cu12Sb4S13 shows a metal–semiconductor transition (MST) at TMST = 85 K. We have studied the mechanism of the MST by measurements of Cu-NMR. Above TMST, the Cu-NMR spectrum consists of ...

Keywords: tetrahedrite cu12sb4s13; metal semiconductor; transition; semiconductor transition

Journal Title: Journal of the Physical Society of Japan
Year Published: 2019

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