Platinum Complexes with Chelating Acyclic Aminocarbene Ligands Work as Catalysts for Hydrosilylation of Alkynes
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DOI: 10.1021/acsomega.7b01688
Abstract: This work describes the preparation of a series of platinum–aminocarbene complexes [PtCl{C(N=Ca(C6R2R3R4R5CONb))=N(H)R1}(CNR1)]a–b (8–19, 65–75% isolated yield) via the reaction of cis-[PtCl2(CNR1)2] (R1 = Cy 1, t-Bu 2, Xyl 3, 2-Cl-6-MeC6H34) with 3-iminoisoindolin-1-ones HN=Ca(C6R2R3R4R5CONbH) (R2–R5 =… read more here.
Keywords: work; aminocarbene; platinum; catalysts hydrosilylation ... See more keywords