Charge transfer complexes of metal-free phthalocyanine radical anions with decamethylmetallocenium cations: (Cp*2Co+)(H2Pc˙-)·solvent and (Cp*2Cr+)(H2Pc˙-)·4C6H4Cl2.
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DOI: 10.1039/c7dt00336f
Abstract: Charge transfer complexes (Cp*2Co+)(H2Pc˙-)·0.5C6H4Cl2·0.7C6H5CN·0.3C6H14 (1) and (Cp*2Cr+)(H2Pc˙-)·4C6H4Cl2 (2) have been obtained as single crystals. Both complexes contain metal-free phthalocyanine (Pc) radical anions and decamethylmetallocenium cations. Reduction of the Pc macrocycle leads to the appearance of… read more here.
Keywords: transfer complexes; 2co h2pc; h2pc 4c6h4cl2; h2pc ... See more keywords