A molecular electron density theory study of the [3 + 2] cycloaddition reaction of nitrones with strained allenes
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DOI: 10.1039/c7ra01916e
Abstract: The [3 + 2] cycloaddition (32CA) reaction of C-phenyl-N-tert-butylnitrone with 1,2-cyclohexadiene (CHDE), a strained allene, has been studied within Molecular Electron Density Theory (MEDT) at the DFT B3LYP/6-311G(d,p) computational level. This non-polar 32CA reaction, which… read more here.
Keywords: cycloaddition; 32ca reaction; density theory; reaction ... See more keywords
[3 + 2] Cycloadditions in Asymmetric Synthesis of Spirooxindole Hybrids Linked to Triazole and Ferrocene Units: X-ray Crystal Structure and MEDT Study of the Reaction Mechanism
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DOI: 10.3390/sym14102071
Abstract: Derivatization of spirooxindole having triazole and ferrocene units was achieved by the [3 + 2] cycloaddition (32CA) reaction approach. Reacting the respective azomethine ylide (AY) intermediate generated in situ with the ethylene derivative produced novel… read more here.
Keywords: structure; ferrocene units; reaction; 32ca reaction ... See more keywords