2:1 Charge disproportionation in perovskite-structure oxide La1/3Ca2/3FeO3 with unusually-high-valence Fe3.67+
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DOI: 10.1016/j.jssc.2016.11.027
Abstract: Abstract La1/3Ca2/3FeO3 with unusually-high-valence Fe3.67+ was synthesized at a high pressure and high temperature. The compound crystallizes in a √2a×2a×√2a perovskite cell in which the La and Ca ions at the A site are disordered.… read more here.
Keywords: charge disproportionation; 3feo3 unusually; fe3; 3ca2 3feo3 ... See more keywords