Bi0.5Pb0.5FeO3 with Unusual Pb Charge Disproportionation: Indication of a Systematic Charge Distribution Change in Bi0.5Pb0.5MO3 (M: 3d Transition Metal).
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DOI: 10.1021/acs.inorgchem.2c01911
Abstract: Bi0.5Pb0.5FeO3 with 1:1 mixture of Bi and Pb having charge degrees of freedom at the A-site of perovskite oxide ABO3 is obtained for the first time by high-pressure synthesis. Comprehensive synchrotron X-ray powder diffraction, optical… read more here.
Keywords: spectroscopy; transition metal; 5pb0 5feo3; charge ... See more keywords