Perovskitizer Tuning Pb2+ 6s2 Lone Pair Effects in Hybrid Perovskite Halide Enables Multiaxial Self‐Powered X‐Ray Detection
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202404353
Abstract: The stereochemical expression of the ns2 lone pair significantly impacts symmetry breaking and corresponding photoelectric properties. However, hindered by the symmetric octahedral configuration, the Pb2+ 6s2 lone pair in the well‐conductive lead halide hybrid perovskites… read more here.
Keywords: 6s2 lone; lone pair; lone; ray detection ... See more keywords
On the consequences of the stereochemical activity of the Bi(iii) 6s2 lone pair in cyclen-based complexes. The [Bi(DO3A)] case.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt02602e
Abstract: We report a detailed study of the structure of the [Bi(DO3A)] complex both in the solid state and in solution. The X-ray crystal structure of [Bi(DO3A)] evidences the octa-coordination of the Bi(iii) ion, which is… read more here.
Keywords: 6s2 lone; coordination; lone pair; do3a complex ... See more keywords