Observation of an Unusual Uranyl Cation-Cation Interaction in the Strongly Fluorescent Layered Uranyl Phosphates Rb6[(UO2)7O4(PO4)4] and Cs6[(UO2)7O4(PO4)4].
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DOI: 10.1021/acs.inorgchem.8b00302
Abstract: Single crystals of two new uranyl phosphates, A6[(UO2)7O4(PO4)4] (A = Cs, Rb), featuring cation-cation interactions (CCIs) rarely observed in uranium(VI) compounds were synthesized by molten flux methods. This structure crystallizes in the triclinic space group… read more here.
Keywords: cation cation; 7o4 po4; uo2 7o4; uranyl phosphates ... See more keywords