Reversible [4 + 2] Photooxygenation in Anion-Coordination-Driven-Assembled A2L2-Type Complexes.
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DOI: 10.1021/acs.inorgchem.1c03392
Abstract: Two bis-bis(urea) ligands (L1 and L2) incorporating the photoactive 9,10-diphenylanthracene fragment were designed for the construction of anion-coordination-driven assemblies and subsequent oxygenation of anthracene moieties for singlet oxygen storage. The corresponding A2L2-type sulfate complexes [TEA]4[(SO4)2(L1)2]… read more here.
Keywords: coordination driven; a2l2 type; anion coordination;