Abnormal N-Heterocyclic Carbene–Palladium Complexes for the Copolymerization of Ethylene and Polar Monomers
Sign Up to like & getrecommendations! Published in 2020 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c00802
Abstract: Palladium complexes bearing abnormal imidazo[1,5-a]pyridine (aImPy)-based N-heterocyclic carbene ligands were developed for the homopolymerization of olefins and the copolymerization of olefins and... read more here.
Keywords: abnormal heterocyclic; palladium complexes; copolymerization; heterocyclic carbene ... See more keywords
Regioselective ring-opening of epoxides towards Markovnikov alcohols: a metal-free catalytic approach using abnormal N-heterocyclic carbene.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03549a
Abstract: Herein we report the first metal-free regioselective Markovnikov ring-opening of epoxides (selectivity up to 99%) using an abnormal N-heterocyclic carbene (aNHC) to yield secondary alcohols. DFT calculations and X-ray crystallography suggest that the Markovnikov selectivity… read more here.
Keywords: opening epoxides; metal free; abnormal heterocyclic; using abnormal ... See more keywords