Mixed Donor–Acceptor-Derived N,N′-Diarylpyrazine-2,5-dicarboxamido-Bridged Diruthenium Systems: Structures, Magnetic Properties, and Electronic Forms in Multiredox States
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201701009
Abstract: Herein, we report diruthenium(III) complexes bridged by the deprotonated N,N′-diphenylpyrazine-2,5-dicarboxamide (H2L1) and N,N′-dimesitylpyrazine-2,5-dicarboxamide (H2L2) ligands in meso diastereomeric form, namely, (acac)2RuIII(µ-L1)RuIII(acac)2 (1, acac = acetylacetonato) and (acac)2RuIII(µ-L2)RuIII(acac)2 (2), as well as the monodeprotonated HL1-derived mononuclear… read more here.
Keywords: acac 2ruiii; derived diarylpyrazine; acceptor derived; donor acceptor ... See more keywords
Indazole-Derived Mono-/Diruthenium and Heterotrinuclear Complexes: Switchable Binding Mode, Electronic Form, and Anion Sensing Events.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02628
Abstract: The article deals with the newer classes of mononuclear: [(acac)2RuIII(H-Iz)(Iz-)] 1, [(acac)2RuIII(H-Iz)2]ClO4 [1]ClO4/[1']ClO4, and [(bpy)2RuII(H-Iz)(Iz-)]ClO4 [2]ClO4, mixed-valent unsymmetric dinuclear: [(acac)2RuIII(μ-Iz-)2RuII(bpy)2]ClO4 [3]ClO4, and heterotrinuclear: [(acac)2RuIII(μ-Iz-)2MII(μ-Iz-)2RuIII(acac)2] (M = Co:4a, Ni:4b, Cu:4c, and Zn:4d) complexes (H-Iz = indazole,… read more here.
Keywords: clo4; clo4 clo4; anion; acac 2ruiii ... See more keywords