[Pd(acac)(PR3)(PhCN)][BF4] and [Pd(acac)(S)2][BF4] (R = phenyl, 2-methoxyphenyl; S = benzonitrile, pyridine): Synthesis, characterization, reactivity and catalytic behavior. Crystal structure of Pd(κ2-O,O′-acac)(κ1-C-acac)(P(2-MeOC6H4)3)
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DOI: 10.1016/j.molstruc.2020.128425
Abstract: Abstract The Pd(II)complexes [Pd(acac)(PR3)(PhCN)][BF4] and [Pd(acac)(S)2][BF4] (acac = acetylacetonate; R = phenyl, 2-methoxyphenyl; S = benzonitrile, pyridine, CD3CN) were synthesized by the reaction of Pd(acac)2 or Pd(acac)2·PR3 with 2 equiv. of BF3·OEt2 in the presence of appropriate ligands (S). The structural… read more here.
Keywords: bf4 acac; acac; bf4; acac pr3 ... See more keywords