Self-Accelerating Click Reaction in Step Polymerization
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DOI: 10.1021/acs.macromol.7b01173
Abstract: A self-accelerating double-strain-promoted azide–alkyne cycloaddition reaction (DSPAAC) was used in the step polymerization for the first time. This produced a novel stoichiometric imbalance-promoted homogeneous step polymerization method using sym-dibenzo-1,5-cyclooctadiene-3,7-diyne (DIBOD) and various bis-azide compounds (N3-R-N3)… read more here.
Keywords: polymerization; step polymerization; self accelerating; reaction ... See more keywords