Ordered Donor–Acceptor Complex Formation and Electron Transfer in Co-deposited Films of Structurally Dissimilar Molecules
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.0c02465
Abstract: The electrical and optoelectronic properties of organic semiconductor thin films can be tailored by mixing two molecular materials, e.g., by co-deposition. Possible resulting morphologies include p... read more here.
Keywords: formation electron; acceptor complex; ordered donor; electron transfer ... See more keywords
Nickel-Catalyzed Decarboxylative Cross-Coupling of Bicyclo[1.1.1]pentyl Radicals Enabled by Electron Donor-Acceptor Complex Photoactivation.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01558
Abstract: The use of bicyclo[1.1.1]pentanes (BCPs) as para-disubstituted aryl bioisosteres has gained considerable momentum in drug development programs. Carbon-carbon bond formation via transition-metal-mediated cross-coupling represents an attractive strategy to generate BCP-aryl compounds for late-stage functionalization, but… read more here.
Keywords: acceptor complex; electron donor; cross coupling; donor acceptor ... See more keywords
Nickel-Catalyzed Three-Component Alkylacylation of Alkenes Enabled by a Photoactive Electron Donor-Acceptor Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01237
Abstract: An electron donor-acceptor complex-enabled, nickel-catalyzed three-component net-reductive 1,2-alkylacylation of alkenes is developed. This conjunctive reductive acyl cross-coupling process obviates the use of an exogenous photocatalyst and a stoichiometric metal-based reductant, affording various synthetically useful 1,3-dicarbonyl… read more here.
Keywords: electron donor; nickel catalyzed; catalyzed three; donor acceptor ... See more keywords
Visible-Light-Driven Synthesis of Aryl Xanthates and Aryl Dithiocarbamates via an Electron Donor-Acceptor Complex.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03736
Abstract: Herein, we report a facile, efficient, and practical protocol that enables the preparation of aryl xanthates and aryl dithiocarbamates from functionalized dibenzothiophenium salts via a photoactivated electron donor-acceptor complex. This mild, metal-free method is operationally… read more here.
Keywords: aryl dithiocarbamates; electron donor; donor acceptor; aryl xanthates ... See more keywords
Organocatalytic β-Azidation of Enones Initiated by an Electron-Donor-Acceptor Complex.
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DOI: 10.1021/acs.orglett.7b02861
Abstract: An operationally straightforward organocatalytic β-azidation of α,β-unsaturated ketones is described. Reaction of the Zhdankin azidoiodane with enones in the presence of a catalytic amount of an amine provides β-azido ketones via the formation of an… read more here.
Keywords: acceptor complex; electron donor; organocatalytic azidation; donor acceptor ... See more keywords
Acceptor complex signatures in oxygen-rich ZnO thin films implanted with chlorine ions
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Applied Physics"
DOI: 10.1063/5.0021089
Abstract: Spectroscopic identification of defects and impurities is crucial for understanding doping asymmetry issues in ZnO and, therefore, realization of true ZnO-based bipolar devices. Chlorine (Cl) is an amphoteric impurity in ZnO exhibiting acceptor behavior in… read more here.
Keywords: acceptor complex; thin films; complex signatures; zno ... See more keywords