Mixed Donor–Acceptor-Derived N,N′-Diarylpyrazine-2,5-dicarboxamido-Bridged Diruthenium Systems: Structures, Magnetic Properties, and Electronic Forms in Multiredox States
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201701009
Abstract: Herein, we report diruthenium(III) complexes bridged by the deprotonated N,N′-diphenylpyrazine-2,5-dicarboxamide (H2L1) and N,N′-dimesitylpyrazine-2,5-dicarboxamide (H2L2) ligands in meso diastereomeric form, namely, (acac)2RuIII(µ-L1)RuIII(acac)2 (1, acac = acetylacetonato) and (acac)2RuIII(µ-L2)RuIII(acac)2 (2), as well as the monodeprotonated HL1-derived mononuclear… read more here.
Keywords: acac 2ruiii; derived diarylpyrazine; acceptor derived; donor acceptor ... See more keywords