Articles with "acceptor substituted" as a keyword



Donor-/Acceptor-Substituted Tetrakis(arylethynyl)benzenes: The Influence of Donor Group on Optoelectronic Properties.

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Published in 2019 at "ChemPlusChem"

DOI: 10.1002/cplu.201900266

Abstract: We have prepared nine structural isomers of a tetrakis(arylethynyl)benzene chromophore functionalized with 4-butoxyphenyl and pyridyl units as the respective donor and acceptor units and examined their steady-state spectroscopic parameters to study how small structural variations… read more here.

Keywords: acceptor substituted; substituted tetrakis; donor acceptor; tetrakis arylethynyl ... See more keywords

Synthesis of Donor/Acceptor-Substituted Diazo Compounds in Flow and Their Application in Enantioselective Dirhodium-Catalyzed Cyclopropanation and C-H Functionalization.

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Published in 2017 at "Organic letters"

DOI: 10.1021/acs.orglett.7b01073

Abstract: A tandem reaction system has been developed for the preparation of donor/acceptor-substituted diazo compounds in continuous flow coupled to dirhodium-catalyzed C-H functionalization or cyclopropanation. Hydrazones were oxidized in flow by solid-supported N-iodo-p-toluenesulfonamide potassium salt (PS-SO2NIK)… read more here.

Keywords: diazo compounds; dirhodium catalyzed; substituted diazo; donor acceptor ... See more keywords

Copper-Catalyzed Coupling of Thioamides and Donor/Acceptor-Substituted Carbenoids: Synthesis of Enamino Esters and Enaminones

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Published in 2019 at "ACS Omega"

DOI: 10.1021/acsomega.8b02633

Abstract: The coupling of thioamides and donor/acceptor-substituted diazocarbonyl compounds is reported for the first time. The present report provides a mild, catalytic method that couples thioamides and donor/acceptor-substituted diazocarbonyl compounds to form enamino esters and enaminones.… read more here.

Keywords: thioamides donor; enamino esters; donor acceptor; acceptor substituted ... See more keywords

An Acceptor-Substituted N-Heterocyclic ortho-Quinodimethane: Pushing the Boundaries of Polarization in Donor-Acceptor-Substituted Polyenes.

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c13783

Abstract: We report the synthesis, isolation, and characterization of a stable donor-acceptor substituted ortho-quinodimethane (oQDM). This system with an imidazolidine scaffold as the donor can also be referred to as acceptor-substituted ortho-N-heterocyclic quinodimethane (oNHQ). We have… read more here.

Keywords: quinodimethane; donor acceptor; acceptor; polarization ... See more keywords
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Donor–acceptor substituted 1,8-naphthalimides: design, synthesis, and structure–property relationship

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Published in 2019 at "Journal of Materials Chemistry C"

DOI: 10.1039/c9tc02634g

Abstract: Research on developing new donor–acceptor (D–A) substituted 1,8-naphthalimide (NI) based molecular systems is a rapidly growing research are due to their wide-ranging applications in the field of organic photonics and electronics. read more here.

Keywords: design synthesis; naphthalimides design; donor acceptor; acceptor substituted ... See more keywords

New Acridone- and (Thio)Xanthone-Derived 1,1-Donor–Acceptor-Substituted Alkenes: pH-Dependent Fluorescence and Unusual Photooxygenation Properties

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Published in 2021 at "Molecules"

DOI: 10.3390/molecules26113305

Abstract: A synthetic route to new heterocyclic 1,1-donor–acceptor-substituted alkenes starting with N-methyl-acridone, xanthone, and thioxanthone was investigated, leading to the acridone- and xanthone-derived products methyl 2-methoxy-2-(10-methylacridin-9 (10H)-ylidene)acetate (7) and methyl 2-methoxy-2-(9H-xanthen-9-ylidene)acetate (10) in low yields with… read more here.

Keywords: fluorescence; xanthone derived; donor acceptor; acceptor substituted ... See more keywords