Accessing cationic tetrylene-nickel(0) systems featuring donor-acceptor E-Ni triple bonds (E = Ge, Sn).
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DOI: 10.1039/d2cc00422d
Abstract: We describe facile synthetic methods for accessing linear cationic tetrylene nickel(0) complexes [SiiPDippE·Ni(PPh3)3]+ (E = Ge (4) and Sn (5); SiiPDipp = [(iPr3Si)(Dipp)N]-), which feature donor-acceptor E-Ni triple bonds. These species are readily accessed in… read more here.
Keywords: acceptor triple; tetrylene nickel; triple bonds; donor acceptor ... See more keywords