Gold-Catalyzed Cycloisomerization of Pyridine-Bridged 1,8-Diynes: An Expedient Access to Luminescent Cycl[3.2.2]azines.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b02677
Abstract: Gold-catalyzed diyne cycloisomerizations involving carbene/alkyne metathesis have been the focal point of attention for the past few years as it offers great potential to build complex polycyclic architectures. However, the design of novel cycloisomerizations has… read more here.
Keywords: bridged diynes; pyridine bridged; access luminescent; cycloisomerization pyridine ... See more keywords
Easy wide scope access to luminescent fluorophosphoranes.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc00976a
Abstract: The almost quantitative synthesis of homologous luminescent fluorophosphoranes, by SNAr cyclization of (2'-F,2-(PR2)biaryl) phosphines made from easily accessible reagents, is reported and the DFT cyclization mechanism and alternative pathways to complete this isomerization are studied… read more here.
Keywords: access luminescent; scope access; luminescent fluorophosphoranes; easy wide ... See more keywords