Syntheses of ent-Aquilanol A and ent-Aquilanol B via Retro-Cycloisomerization of (-)-Caryophyllene Oxide. Access to Medium-Sized Oxygenated Carbocyclic Scaffolds.
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DOI: 10.1021/acs.orglett.2c02216
Abstract: The first syntheses of the enantiomers of naturally occurring aquilanols A and B, two unprecedented 7/10 bicyclic sesquiterpenoids, are presented. Key features are a retro-cycloisomerization event on (-)-caryophyllene oxide to formulate the 11-membered carbocycle and… read more here.
Keywords: retro cycloisomerization; ent aquilanol; medium sized; access medium ... See more keywords