Access to a pair of ambiphilic phosphine-borane regioisomers by rhodium-catalyzed hydroboration.
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DOI: 10.1039/c8dt01467a
Abstract: Lewis basic substrates, such as vinylphosphines and enamines, can be problematic for transition-metal catalysed hydrofunctionalization reactions due to their propensity to ligate and deactivate transition-metal catalysts as well as form direct Lewis adducts with reaction… read more here.
Keywords: access pair; phosphine; rhodium catalyzed; pair ambiphilic ... See more keywords