Accessing aliphatic alcohols for metallaphotoredox catalyzed C(sp3)-arylation
Sign Up to like & getrecommendations! Published in 2021 at "Chem"
DOI: 10.1016/j.chempr.2021.09.006
Abstract: Common cross-coupling reactions to obtain C(sp2)–C(sp3)-bonds are hampered by the abundance of nucleophilic and electrophilic functional groups. Recently in Nature, Dong and MacMillan developed a mild activation of a diverse range of alcohols with an… read more here.
Keywords: aliphatic alcohols; catalyzed sp3; arylation; metallaphotoredox catalyzed ... See more keywords
Accessing Aliphatic Amines in C-C Cross-Couplings by Visible Light/Nickel Dual Catalysis.
Sign Up to like & getrecommendations! Published in 2021 at "Organic letters"
DOI: 10.1021/acs.orglett.1c01207
Abstract: A general aminoalkylation of aryl halides was developed, overcoming intolerance of free amines in nickel-mediated C-C coupling. This transformation features broad functional group tolerance and high efficiency. Taking advantage of the fast desilylation of α-silylamines… read more here.
Keywords: cross couplings; couplings visible; accessing aliphatic; visible light ... See more keywords