Efficient and chemoselective hydroboration of organic nitriles promoted by TiIV catalyst supported by unsymmetrical acenaphthenequinonediimine ligand
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DOI: 10.1016/j.jorganchem.2019.120958
Abstract: Abstract We report the synthesis, characterization, and utilization of a titanium (IV) complex [(η5-C5H5){L}TiCl2] (1) supported by a monoanionic ligand (L), N-(2, 6-diisopropyl)acenaphthenequinonediimido, as a molecular pre-catalyst for the hydroboration of nitriles. The unsymmetrical N-silylated… read more here.
Keywords: catalyst; titanium complex; acenaphthenequinonediimine ligand; ligand ... See more keywords