Palladium‐Catalyzed Aerobic Synthesis of Terminal Acetals from Vinylarenes Assisted by π‐Acceptor Ligands
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DOI: 10.1002/cctc.201601517
Abstract: Terminal acetals were synthesized from various vinylarenes and 1,2‐ or 1,3‐diols using a simple PdCl2(MeCN)2/methoxy‐p‐benzoquinone (MeOBQ)/CuCl catalyst system and 1 atm of O2 under mild reaction conditions by the anti‐Markovnikov nucleophilic attack of an oxygen nucleophile… read more here.
Keywords: aerobic synthesis; synthesis terminal; terminal acetals; palladium catalyzed ... See more keywords