A re-investigation of the Fries rearrangement of 3-chlorophenyl acetate and synthesis of 2-azido-1-(4-(benzyloxy)-2-chlorophenyl)ethanone from 4-bromo-3-chlorophenol
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2017.11.016
Abstract: Abstract The Fries rearrangement of 3-chlorophenyl acetate provided the expected 4-chloro-2-hydroxy-acetophenone as the major product and 2,4-diacetyl resorcinol and 2-chloro-4-hydroxy-acetophenone as minor products. 4-Benzyloxy-2-chloroacetophenone was prepared by a Heck reaction and then elaborated to 4-benzyloxy-2-chlorophenacyl… read more here.
Keywords: synthesis azido; fries rearrangement; investigation fries; acetate synthesis ... See more keywords
Using sodium acetate for the synthesis of [Au(NHC)X] complexes.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02240c
Abstract: The role of sodium acetate in the synthesis of [Au(NHC)Cl] complexes was examined. The use of this base was also investigated for the activation of C-H and S-H bonds by experimental and computational methods. The… read more here.
Keywords: nhc complexes; acetate synthesis; synthesis nhc; sodium acetate ... See more keywords