Copper-Mediated Decarboxylative Coupling of 3-Indoleacetic Acids with Sulfoxonium Ylides for the Synthesis of α-Acetoxyl Ketones.
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DOI: 10.1021/acs.orglett.4c01867
Abstract: The most convenient and direct method of synthesizing an α-acyloxy ketone is the reaction of a diazo compound with a carboxylic acid via O-H insertion. However, due to the limitations in preparing and storing diazo… read more here.
Keywords: sulfoxonium ylides; indoleacetic acids; decarboxylative coupling; acetoxyl ketones ... See more keywords