Phosphorescent heteroleptic iridium(III) cyclometallates: Improved syntheses of acetylacetonate complexes and quantum chemical studies of their excited state properties
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114256
Abstract: Abstract We have investigated methods to prepare cyclometallated iridium(III) complexes with efficient photoluminescence spanning a broad color palette. In particular, we find that addition of ancillary ligands to chloro-bridged iridium dimers proceeds cleanly in refluxing… read more here.
Keywords: state; iridium iii; iridium; acetylacetonate complexes ... See more keywords
Yb3+ can be much better than Dy3+: SMM properties and controllable self-assembly of novel lanthanide 3,5-dinitrobenzoate-acetylacetonate complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00624e
Abstract: The first representatives of the binuclear lanthanide 3,5-dinitrobenzoate-acetylacetonate complexes, namely isostructural compounds [Ln(dnbz)(acac)2(H2O)(EtOH)]2 (Ln = Eu (1), Gd (2), Tb (3), Dy (4), Ho (5), Er (6), Tm (7), and Yb (8); dnbz - 3,5-dinitrobenzoate… read more here.
Keywords: dinitrobenzoate acetylacetonate; smm; dinitrobenzoate; acetylacetonate complexes ... See more keywords