Efficient adsorption separation of acetylene and ethylene via supported ionic liquid on metal‐organic framework
Sign Up to like & getrecommendations! Published in 2017 at "Aiche Journal"
DOI: 10.1002/aic.15561
Abstract: Ionic liquid (IL) supported metal-organic framework (MOF) was utilized to efficiently separate acetylene from ethylene. A common ionic liquid, 1-butyl-3-methylimidazolium acetate ([Bmim][OAc]), was encapsulated into a hydrothermally stable MOF, namely MIL-101(Cr). Characterization techniques including FTIR,… read more here.
Keywords: ionic liquid; adsorption; metal organic; acetylene ethylene ... See more keywords
Application of pristine and Ni-decorated B12P12 nano-clusters as superior media for acetylene and ethylene adsorption: DFT calculations
Sign Up to like & getrecommendations! Published in 2017 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2017.03.030
Abstract: Abstract In this study, density functional theory (DFT) method with B3LYP-D and MPW1PW91 functionals is carried out to explicate the adsorption properties of small unsaturated hydrocarbons (acetylene and ethylene molecules) on the surfaces of pristine… read more here.
Keywords: decorated b12p12; adsorption; ethylene adsorption; b12p12 nano ... See more keywords
The optimal adsorption pathway of H2 molecules on Ti-Acetylene/ ethylene compounds: A DFT study
Sign Up to like & getrecommendations! Published in 2020 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.11.085
Abstract: Abstract Ti-Acetylene/Ethylene complexes were used to be considered as a potential high capacity hydrogen storage media by physisorption. Here, special attentions have been paid to the optimal adsorption pathway of H2 molecules on TiC2H2/TiC2H4 compounds… read more here.
Keywords: acetylene ethylene; pathway molecules; adsorption pathway; optimal adsorption ... See more keywords
Defect-free mixed-matrix membranes consisting of anion-pillared metal-organic frameworks and poly(ionic liquid)s for separation of acetylene from ethylene
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Membrane Science"
DOI: 10.1016/j.memsci.2020.118329
Abstract: Abstract Membrane separation is an effective strategy to reduce the energy consumption during conventional processes in the petrochemical industry. Currently, membrane separations of light hydrocarbons are still underdeveloped and the general problem of the poor… read more here.
Keywords: defect free; mixed matrix; acetylene ethylene; separation ... See more keywords
Comparative Study on Nascent Soot Formation Characteristics in Laminar Premixed Acetylene, Ethylene, and Ethane Flames
Sign Up to like & getrecommendations! Published in 2018 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.8b02852
Abstract: The sooting behavior in the laminar premixed flames of acetylene, ethylene, and ethane was studied both experimentally and computationally to explore the effect of fuel structure on nascent soot formation. The particle size distributions were… read more here.
Keywords: ethane; ethylene ethane; nascent soot; acetylene ethylene ... See more keywords
Selective hydrogenation of acetylene to ethylene by alkali-metal palladium complex hydrides.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc07080d
Abstract: A series of alkali-metal palladium complex hydrides have been shown to be catalytically active and selective for partial hydrogenation of acetylene to ethylene. The complex hydrides differ in composition, structure, and catalytic function as compared… read more here.
Keywords: metal palladium; hydrogenation acetylene; acetylene ethylene; palladium complex ... See more keywords
Tailoring the pore chemistry in porous aromatic frameworks for selective separation of acetylene from ethylene
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc03944c
Abstract: The separation of acetylene from ethylene is a crucial process in the petrochemical industry, because even traces of acetylene impurities can poison the catalysts of ethylene polymerization. Herein, we synthesize a new family of 3D… read more here.
Keywords: separation acetylene; chemistry; acetylene ethylene; porous aromatic ... See more keywords