Micropore Regulation in Ultrastable [Sc3O]-Organic Frameworks for Acetylene Storage and Purification.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03562
Abstract: High storage capacity, high separation selectivity, and high structure stability are essential for an idea gas adsorbent. However, it is not easy to achieve all three at the same time, even for the promising metal-organic… read more here.
Keywords: storage purification; acetylene storage; organic frameworks; snnu 150 ... See more keywords
Acetylene storage performance of [Ni(4,4'-bipyridine)2(NCS)2]n, a switching square lattice coordination network.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06638b
Abstract: We report that the previously reported square lattice coordination network [Ni(4,4'-bipyridine)2(NCS)2]n, sql-1-Ni-NCS, undergoes acetylene induced switching between closed (nonporous) and open (porous) phases. The resulting stepped sorption isotherms exhibit temperature controlled steps, consistent high uptake… read more here.
Keywords: bipyridine ncs; acetylene storage; lattice coordination; square lattice ... See more keywords