Revisiting the mechanism of acetylenic amine N-Oxide rearrangement catalysed by Gold(I) complexes from a DFT perspective
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DOI: 10.1016/j.jorganchem.2019.03.011
Abstract: Abstract In this study, we used density functional theory (DFT) to reinvestigate the mechanism proposed by Houk and Zhang et al. (J. Am. Chem. Soc. 2012, 134, 1078) for piperidinone formation through rearrangement of an acetylenic amine… read more here.
Keywords: amine oxide; acetylenic amine; gold complexes; rearrangement ... See more keywords