Articles with "acetylketenimine highly" as a keyword



Photo by ourselp from unsplash

N-Sulfonyl acetylketenimine as a highly reactive intermediate for synthesis of N-Aroylsulfonamides

Sign Up to like & get
recommendations!
Published in 2019 at "Tetrahedron"

DOI: 10.1016/j.tet.2018.12.005

Abstract: Abstract A highly reactive intermediate N-sulfonyl acetylketenimine was generated from an ynone-participated CuAAC/ring-opening method. Its unique structure allowed it to react with aryl carboxylic acids to give N-aroylsulfonamides via a novel Mumm-type rearrangement. read more here.

Keywords: highly reactive; acetylketenimine highly; intermediate synthesis; synthesis aroylsulfonamides ... See more keywords