Complexation of Chiral Zinc(II) Porphyrin Tweezer with Achiral Aliphatic Diamines Revisited: Molecular Dynamics, Electronic CD, and 1H NMR Analysis.
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DOI: 10.1021/acs.inorgchem.9b00962
Abstract: We have reported here the complexation and chiroptical behavior of the host-guest complexes using a new chiral Zn(II) bisporphyrin tweezer host and a series of achiral aliphatic diamine guests varying the chain length. (1R,2R)-Cyclohexanediamine covalently… read more here.
Keywords: achiral aliphatic; molecular dynamics; complexation; porphyrin ... See more keywords