Chiral Hierarchical Architecture Induced by Confinement-Assisted Living Supramolecular Polymerization of Simple Achiral Molecules.
Sign Up to like & getrecommendations! Published in 2023 at "ACS nano"
DOI: 10.1021/acsnano.2c12063
Abstract: Chiral supramolecular assembly (CSA) based on achiral molecules has provided important clues to understand the origin of biological chirality. However, a simple achiral monomer faces the challenge of chiral stacking with the absence of a… read more here.
Keywords: achiral molecules; supramolecular polymerization; living supramolecular; simple achiral ... See more keywords
Chiral photochemistry of achiral molecules.
Sign Up to like & getrecommendations! Published in 2022 at "Nature communications"
DOI: 10.1038/s41467-022-29662-1
Abstract: Chirality is a molecular property governed by the topography of the potential energy surface (PES). Thermally achiral molecules interconvert rapidly when the interconversion barrier between the two enantiomers is comparable to or lower than the… read more here.
Keywords: achiral molecules; topography; chiral photochemistry; photochemistry achiral ... See more keywords
Electronic chirality inversion of lanthanide complex induced by achiral molecules
Sign Up to like & getrecommendations! Published in 2018 at "Scientific Reports"
DOI: 10.1038/s41598-018-34790-0
Abstract: A novel mechanism for chiroptical activity inversion based on the electronic structure of metal complexes without Λ- or Δ-type structure change was demonstrated spectroscopically and theoretically. To demonstrate the mechanism, a europium (Eu(III)) complex with… read more here.
Keywords: inversion; achiral molecules; structure; iii complex ... See more keywords