The Asymmetry is Derived from Mechanical Interlocking of Achiral Axle and Achiral Ring Components -Syntheses and Properties of Optically Pure [2]Rotaxanes-
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DOI: 10.3390/sym10010020
Abstract: Rotaxanes consisting of achiral axle and achiral ring components can possess supramolecular chirality due to their unique geometrical architectures. To synthesize such chiral rotaxanes, we adapted a prerotaxane method based on aminolysis of a metacyclophane… read more here.
Keywords: achiral axle; ring components; achiral ring; chiral rotaxanes ... See more keywords