Oxidative NHC catalysis: direct activation of β sp3 carbons of saturated acid chlorides.
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DOI: 10.1039/c8cc08578a
Abstract: The first activation of saturated acid chlorides by oxidative N-heterocyclic carbene catalysis has been successfully utilized to synthesize enantio-enriched spirooxindole lactones and δ-lactones. The reaction involves the transformation of the β sp3 carbon of saturated… read more here.
Keywords: sp3; chlorides oxidative; catalysis; activation ... See more keywords
Highly Active Manganese-Mediated Acylation of Alcohols with Acid Chlorides or Anhydrides
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DOI: 10.1055/s-0036-1590973
Abstract: To explore further the practical uses of highly active manganese (Mn*), a variety of alcohols were treated with Mn*, and the resulting complexes were coupled with acid chlorides and/or acetic anhydride in the absence of… read more here.
Keywords: active manganese; manganese mediated; highly active; mediated acylation ... See more keywords