Articles with "acid decomposition" as a keyword



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Mechanistic implications of lanthanum-modification on gold-catalyzed formic acid decomposition under SCR-relevant conditions

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Published in 2019 at "Applied Catalysis B: Environmental"

DOI: 10.1016/j.apcatb.2018.11.092

Abstract: Abstract The use of formate-based ammonia precursors as alternatives to urea in the selective catalytic reduction (SCR) process requires that formic acid released upon their thermolysis in the hot exhaust is rapidly decomposed to carbon… read more here.

Keywords: formic acid; relevant conditions; decomposition; acid decomposition ... See more keywords
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DFT study of hydrogen production from formic acid decomposition on Pd-Au alloy nanoclusters

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Published in 2017 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2017.07.165

Abstract: Abstract Recently, it has been reported that the hydrogen production rate of formic acid decomposition can be significantly increased using Pd-Au binary alloy nano-catalysts [Wang et al. J. Mater. Chem. A 1 (2013) 12721–12725]. To… read more here.

Keywords: acid decomposition; alloy nanoclusters; hydrogen production; formic acid ... See more keywords
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Hydrogen-generating behavior of Pd-decorated gold nanoparticles via formic acid decomposition

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Published in 2019 at "Catalysis Today"

DOI: 10.1016/j.cattod.2018.06.044

Abstract: Abstract Formic acid is a promising hydrogen storage material where hydrogen is generated via metal-catalyzed decomposition. Bimetallic catalysts are active for this reaction, but the mechanism has not been fully proven. Palladium metal supported on… read more here.

Keywords: metal; formic acid; gold nanoparticles; acid decomposition ... See more keywords
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Enhancing activity, selectivity and stability of palladium catalysts in formic acid decomposition: Effect of support functionalization

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Published in 2021 at "Catalysis Today"

DOI: 10.1016/j.cattod.2021.07.005

Abstract: Abstract In this work, palladium nanoparticles were deposited on oxygen and phosphorous functionalised carbon nanofibers (CNFs) by sol immobilisation method in order to investigate the support-metal effect on the formic acid (FA) decomposition reaction. In… read more here.

Keywords: formic acid; acid decomposition; stability; support ... See more keywords
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Understanding the influence of the composition of the Ag Pd catalysts on the selective formic acid decomposition and subsequent levulinic acid hydrogenation

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Published in 2020 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2020.04.180

Abstract: Abstract Formic acid is obtained in equimolar amount with levulinic acid during the hydrolysis of cellulose and thus can be used as a sustainable hydrogen source in the direct levulinic acid hydrogenation towards gamma-valerolactone (biofuel… read more here.

Keywords: acid; hydrogenation; formic acid; levulinic acid ... See more keywords
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Superior activity of Pd nanoparticles confined in carbon nanotubes for hydrogen production from formic acid decomposition at ambient temperature.

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Published in 2019 at "Journal of colloid and interface science"

DOI: 10.1016/j.jcis.2018.12.017

Abstract: Designing highly efficient and low-cost catalysts is essential toward realizing the practical application of hydrogen generation by formic acid decomposition (FAD) under ambient conditions. Herein, we report the synthesis of a hybrid material of Pd… read more here.

Keywords: temperature; carbon nanotubes; formic acid; ambient temperature ... See more keywords
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Sorption of Cu by humic acid from the decomposition of rice straw in the absence and presence of clay minerals.

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Published in 2017 at "Journal of environmental management"

DOI: 10.1016/j.jenvman.2017.05.087

Abstract: The sorption of Cu on humic acid (HA) from the decomposition of rice straw in the absence (Ck-HA) and presence of montmorillonite (M-HA), kaolinite (K-HA), gibbsite (Gi-HA) and goethite (Go-HA) was investigated at pH 5.0… read more here.

Keywords: decomposition; sorption; decomposition rice; acid decomposition ... See more keywords
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Analysis of nitric acid decomposition of epoxy resin network structures for chemical recycling

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Published in 2021 at "Polymer Degradation and Stability"

DOI: 10.1016/j.polymdegradstab.2021.109537

Abstract: Abstract Epoxy resin is an essential material for the society, although it poses challenges for recycling because of its cross-linked three-dimensional (3D) structure. Nitric acid decomposition is an effective recycling method for such a 3D… read more here.

Keywords: epoxy resin; nitric acid; acid decomposition; resin ... See more keywords
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Comparative Kinetic Monte Carlo Study of Acetic Acid Decomposition to Surface Carbon Species and Undesirable Byproducts on Pd(100) and Pd/Au(100) from Density Functional Theory-Based Calculations

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Published in 2017 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.7b05072

Abstract: Acetic acid decomposition on Pd(100) and Pd/Au(100) during vinyl acetate (VA) synthesis from ethylene acetoxylation is the primary source of such undesirable byproducts as methanol (CH3OH), acetaldehyde (CH3CHO), ketene (CH2CO), acetone (CH3COCH3), and methane (CH4),… read more here.

Keywords: 100 100; acetic acid; acid decomposition; co2 ... See more keywords
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Hydrogen Production via Efficient Formic Acid Decomposition: Engineering the Surface Structure of Pd-Based Alloy Catalysts by Design

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Published in 2018 at "ACS Catalysis"

DOI: 10.1021/acscatal.8b03485

Abstract: Improving the activity and selectivity of Pd-based alloy catalysts for hydrogen production from formic acid decomposition is still a challenge. We have performed a comprehensive study, on the basis of available experimental data, of the… read more here.

Keywords: alloy catalysts; formic acid; based alloy; acid decomposition ... See more keywords
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Continuous Production of Hydrogen from Formic Acid Decomposition Over Heterogeneous Nanoparticle Catalysts: From Batch to Continuous Flow

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Published in 2019 at "ACS Catalysis"

DOI: 10.1021/acscatal.9b01977

Abstract: We investigate the continuous generation of hydrogen via the low temperature ( read more here.

Keywords: production hydrogen; formic acid; acid decomposition; hydrogen ... See more keywords