Synthesis of two different Ni(II) coordination polymers by introduction of carboxylic acid ligands: Crystal structure and photocatalytic properties
Sign Up to like & getrecommendations! Published in 2019 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.04.042
Abstract: Abstract Two different novel coordination polymers were synthesized under hydrothermal conditions, namely {[Ni(bibp)3(H2O)2]·2NO3·0.5H2O}n (1), [NiL(bibp)]n (2) (H2L = 3,3′-azodibenzoic acid, bibp = 4,4′-bis(imidazolyl)biphenyl). Complex 2 is based on the introduction of carboxylic acid ligands on complex 1. These two… read more here.
Keywords: introduction carboxylic; acid ligands; carboxylic acid; coordination polymers ... See more keywords
A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b03716
Abstract: Kinetic and mechanistic studies of the desymmetrization of benzhydrylamine using Pd/monoprotected amino acid ligands (Pd/MPAA) via C-H functionalization with molecular iodine provide mechanistic insight into the rate-determining step and the oxidation state of Pd in… read more here.
Keywords: acid ligands; amino acid; monoprotected amino; role catalytic ... See more keywords
Metal-organic frameworks constructed from tib and carboxylate acid ligands: selective sensing of nitro explosives and magnetic properties.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01306j
Abstract: Four metal-organic frameworks, namely [Cd2(tib)(btb)(H2O)2]·NO3·2.5DMF (1), [Cd(tib)(H2dhbqdc)0.5(NO3)]·6H2O (2), [Co(tib)(1,4-ndc)]·2DMF (3), and [Cu3(tib)2(2,6-ndc)2(H2O)2]·2NO3·2H2O (4), were synthesized based on 1,3,5-tris(1-imidazolyl)benzene and diverse carboxylic acid ligands. They have been characterized by elemental analysis, infrared spectroscopy (IR), powder X-ray… read more here.
Keywords: acid ligands; magnetic properties; metal organic; topology ... See more keywords
Structural tuning of Zn(ii)-MOFs based on pyrazole functionalized carboxylic acid ligands for organic dye adsorption
Sign Up to like & getrecommendations! Published in 2020 at "CrystEngComm"
DOI: 10.1039/d0ce00798f
Abstract: Two metal–organic frameworks, {(NH2Me2)[Zn(Pycia)]}n (MOF-1) and {(NH2Me2)[Zn2(Pycia)(PBA)]}n (MOF-2), have been synthesized based on pyrazole functionalized carboxylic acid ligands for organic dye adsorption. The enlarged pore dimension of MOF-2 suggests the advantage of additional linear auxiliary… read more here.
Keywords: adsorption; acid ligands; pyrazole functionalized; carboxylic acid ... See more keywords
Cobalt complexes with α-amino acid ligands catalyze the incorporation of CO2 into cyclic carbonates.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03595b
Abstract: Arguably one of the largest research areas involving carbon dioxide (CO2) fixation is the coupling of CO2 to epoxides to form cyclic carbonates and polycarbonates. In this sense, there is an ever-increasing demand for the… read more here.
Keywords: cyclic carbonates; acid ligands; complexes amino; amino acid ... See more keywords