Amination of Aryl Boronic Acids with Alkylnitrites: A Convenient Complement to Cu-Promoted Reductive Amination.
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DOI: 10.1021/acs.orglett.9b03961
Abstract: Copper-catalyzed amination of aryl boronic acids with alkylnitrites leading to symmetrical diarylamines with a practical 50-80% yield was elaborated. Two C(sp2)-N bonds are formed in the one-pot process under mild conditions. This new approach to… read more here.
Keywords: acids alkylnitrites; boronic acids; reductive amination; amination ... See more keywords