Mechanisms of the formation of carboxylic acids and their anhydrides during the liquid-phase oxidation of cyclohexane
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DOI: 10.1007/s11172-019-2582-4
Abstract: The channels of formation and transformation of bifunctional (C5, C6) and monofunctional acids (C1, C5, C6) and their anhydrides during the liquid-phase oxidation of cyclohexane are reviewed. Adipic acid and adipic anhydride are predominantly formed… read more here.
Keywords: anhydrides liquid; oxidation; liquid phase; phase oxidation ... See more keywords
Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides.
Sign Up to like & getrecommendations! Published in 2020 at "Organic letters"
DOI: 10.1021/acs.orglett.0c01277
Abstract: A Rh-catalyzed chelation-assisted C6-selective C-H activation/alkylation of 2-pyridones with readily available alkyl carboxylic acids or anhydrides is introduced. The reaction proceeds via substrate decarbonylation. This approach merges C-H functionalization with readily available anhydrides, allowing for… read more here.
Keywords: alkyl carboxylic; catalyzed selective; carboxylic acids; alkylation pyridones ... See more keywords