Unexpected Trends in the Stability and Dissociation Kinetics of Lanthanide(III) Complexes with Cyclen-Based Ligands across the Lanthanide Series.
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DOI: 10.1021/acs.inorgchem.0c00520
Abstract: We report a detailed study of the thermodynamic stability and dissociation kinetics of lanthanide complexes with two ligands containing a cyclen unit, a methyl group, a picolinate arm, and two acetate pendant arms linked to… read more here.
Keywords: across lanthanide; kinetics lanthanide; dissociation; stability dissociation ... See more keywords
Tetramethylcyclopentadienyl Ligands Allow Isolation of Ln(II) Ions across the Lanthanide Series in [K(2.2.2-cryptand)][(C5Me4H)3Ln] Complexes
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DOI: 10.1021/acs.organomet.8b00557
Abstract: Although previous studies of the stabilization of Ln(II) ions across the lanthanide series have relied on Me3Si-substituted cyclopentadienyl ligands, we now find surprisingly that these ions can also exist surrounded by three tetramethylcyclopentadienyl ligands. Reduction… read more here.
Keywords: across lanthanide; tetramethylcyclopentadienyl ligands; ions across; lanthanide series ... See more keywords