Synthesis and Reactivity of Group Six Metal PCP Pincer Complexes: Reversible CO Addition Across the Metal–Caryl Bond
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DOI: 10.1021/acs.organomet.8b00447
Abstract: In the present study, Cr(III) complexes of the type trans-[Cr(PCPNEt-iPr)(solvent)Cl2] (solvent = CH3CN, THF), the Cr(0) complex [Cr(κ3P,CH,P-P(CH)PNEt-iPr)(CO)3] which features an η2-Caryl–H agostic bond as well as seven coordinate cationic chloro carbonyl Mo(II) and W(II)… read more here.
Keywords: pcpnet ipr; bond; across metal; metal ... See more keywords