Electron-Transfer-Enhanced Cation-Cation Interactions in Homo- and Heterobimetallic Actinide Complexes: A Relativistic Density Functional Theory Study.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00051
Abstract: To provide deep insight into cation-cation interactions (CCIs) involving hexavalent actinyl species that are major components in spent nuclear fuel and pose important implications for the effective removal of radiotoxic pollutants in the environment, a… read more here.
Keywords: cation; actinide; density; actinide complexes ... See more keywords
N-Heterocyclic Carbene to Actinide d-Based π-bonding Correlates with Observed Metal–Carbene Bond Length Shortening Versus Lanthanide Congeners
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DOI: 10.1021/jacs.3c12721
Abstract: Comparison of bonding and electronic structural features between trivalent lanthanide (Ln) and actinide (An) complexes across homologous series’ of molecules can provide insights into subtle and overt periodic trends. Of keen interest and debate is… read more here.
Keywords: heterocyclic carbene; bond length; lanthanide congeners; carbene ... See more keywords