Redox-enabled cooperative catalysis by activating secondary alcohols using low-valent Zn complexes.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc03407d
Abstract: Inspired by nature's redox management in bioinorganic systems, we developed various Zn-complexes to catalyze a radical-mediated borrowing hydrogen process for producing β-disubstituted ketones. A diverse range of secondary alcohols, including fatty alcohols, terpenoids and steroid… read more here.
Keywords: catalysis activating; cooperative catalysis; enabled cooperative; activating secondary ... See more keywords