Ruthenium-Catalyzed Urea Synthesis by N-H Activation of Amines.
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DOI: 10.1021/acs.inorgchem.7b00962
Abstract: Activation of the N-H bond of amines by a ruthenium pincer complex operating via "amine-amide" metal-ligand cooperation is demonstrated. Catalytic formyl C-H activation of N,N-dimethylformamide (DMF) is observed in situ, which resulted in the formation… read more here.
Keywords: activation amines; amines ruthenium; activation; ruthenium catalyzed ... See more keywords