Access to Cyclic N-Trifluoromethyl Ureas through Photocatalytic Activation of Carbamoyl Azides.
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DOI: 10.1021/jacs.2c02004
Abstract: We report the mild activation of carbamoyl azides to the corresponding nitrenes using a blue light/[Ir]-catalyzed strategy, which enables stereospecific access to N-trifluoromethyl imidazolidinones and benzimidazolones. These novel structural motifs proved to be highly robust,… read more here.
Keywords: activation carbamoyl; carbamoyl azides; trifluoromethyl; access cyclic ... See more keywords